کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9770188 | 1501941 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, Raman spectrum, ab initio calculations, and structure of 3,7-dioxabicyclo[3.3.0]oct-1,5-ene
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, Raman spectrum, ab initio calculations, and structure of 3,7-dioxabicyclo[3.3.0]oct-1,5-ene Synthesis, Raman spectrum, ab initio calculations, and structure of 3,7-dioxabicyclo[3.3.0]oct-1,5-ene](/preview/png/9770188.png)
چکیده انگلیسی
The bicyclic bisether molecule 3,7-dioxabicyclo[3.3.0]oct-1,5-ene (DOBO) molecule has been synthesized in small quantities and has been shown to be analytically pure by NMR and mass spectra. The vapor-phase Raman spectrum has been analyzed and compared to the predicted spectra from DFT calculations. This spectrum further confirms the structure of the molecule and shows the skeleton of both rings to be planar with D2h symmetry. Ab initio calculations were carried out to predict the bond distances and angles of the molecule, and these also showed the molecule to be planar.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 742, Issues 1â3, 24 May 2005, Pages 161-164
Journal: Journal of Molecular Structure - Volume 742, Issues 1â3, 24 May 2005, Pages 161-164
نویسندگان
Cornelia Mlynek, Henning Hopf, Juan Yang, Jaan Laane,