کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9770353 | 1501946 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A hydrogen-bonded 3D coordination network of CoII with 4-(p-benzoxy)-1,2,4-triazole: hydrothermal synthesis, characterization, crystal structure and emission property
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A hydrogen-bonded 3D coordination network of CoII with 4-(p-benzoxy)-1,2,4-triazole: hydrothermal synthesis, characterization, crystal structure and emission property A hydrogen-bonded 3D coordination network of CoII with 4-(p-benzoxy)-1,2,4-triazole: hydrothermal synthesis, characterization, crystal structure and emission property](/preview/png/9770353.png)
چکیده انگلیسی
A six-coordinated monomeric CoII complex, [Co(L)2(H2O)4]·10H2O (1), where HL=4-(p-benzoxy)-1,2,4-triazole, has been synthesized and characterized by elemental analyses, IR, thermogravimetric analysis and X-ray diffraction technique. Structural analyses reveal that the CoII center has a CoN2O4 octahedral environment with four O atoms of coordinated water molecules constituting the equatorial plane and two N atoms of two distinct L ligands occupying the two axial sites in 1. A striking structural feature of 1 resides in the formation of a three-dimensional (3D) supramolecular architecture through intermolecular O-Hâ¯O hydrogen-bonding interactions. Complex 1 displays strong blue emission in the solid state.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 737, Issues 2â3, 4 March 2005, Pages 125-129
Journal: Journal of Molecular Structure - Volume 737, Issues 2â3, 4 March 2005, Pages 125-129
نویسندگان
Ru-Qiang Zou, Li-Zhen Cai, Guo-Cong Guo,