کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9770354 1501946 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The investigation of nonlinear optical properties of N-(3-fluorophenyl)naphthaldimine
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
The investigation of nonlinear optical properties of N-(3-fluorophenyl)naphthaldimine
چکیده انگلیسی
A new ligand N-(3-fluorophenyl)naphthaldimine (C17H12NOF) has been synthesized. The physical properties and structure of this ligand have been characterized by X-ray diffraction analysis, elemental analysis, FT-IR, 1H-NMR and UV-visible spectroscopies. It is found that the title compound has solvatochromic behavior in the UV and visible regions, implying non-zero microscopic first hyperpolarizability. The electric dipole moment (μ) and the first hyperpolarizability (β) values of the investigated molecule have been computed using ab initio quantum mechanical calculations (finite field second-order Møller Plesset perturbation theory). The calculation results also reveal that the synthesized molecule might have microscopic nonlinear optical (NLO) behavior with non-zero values.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 737, Issues 2–3, 4 March 2005, Pages 131-137
نویسندگان
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