کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9803176 | 1516463 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and crystal structure of κ-Zr9V4SHâ¼23
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and crystal structure of κ-Zr9V4SHâ¼23 Synthesis and crystal structure of κ-Zr9V4SHâ¼23](/preview/png/9803176.png)
چکیده انگلیسی
The Zr9V4SHâ¼23 hydride was synthesized by saturation from gaseous hydrogen at room temperature and 0.12âMPa hydrogen pressure. The measured hydrogen absorption capacity of the κ-Zr9V4S was 1.77âH/M. The refinement of the hydride structure with the use of X-ray powder diffraction data confirmed the preserved symmetry of the metallic matrix (sp.gr. P63 /mmc, a=9.2715(2), c=9.0756(4)Ã
, Îa/a=7.3%, Îc/c=6.1%, ÎV/V=22.1%, ÎV/at.H=2.62 âÃ
3). The analysis of interstices in this compound revealed that without positioning hydrogen atoms in triangular Zr3 interstices it is impossible to model the structure of k-hydride with the experimentally observed capacity. Neutron powder diffraction study of the Zr9V4SDâ¼23 deuteride (sp.gr. P63/mmc, a=9.2779(5), c=9.0779(5) âÃ
) revealed deuterium atoms filling two tetrahedral and three triangular interstices. A full occupancy of only one site (D4) was observed in our sample giving the refined deuterium content of 20.8(2)âD/f.u. Filling of the D4 site causes a displacement of the sulphur atoms from the three-fold axis (splitting of 2c to 6h position).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volumes 404â406, 8 December 2005, Pages 118-121
Journal: Journal of Alloys and Compounds - Volumes 404â406, 8 December 2005, Pages 118-121
نویسندگان
I.Yu. Zavaliy, R. Äerný, I.V. Koval'chuck, A.B. Riabov, R.V. Denys,