کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9803576 | 1516469 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chemical characterization of selected high copper dental amalgams using XPS and XRD techniques
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The study was carried out to analyze some dependencies between the composition of seven high copper dental amalgams and mercury release behavior, as well as oxygen reactivity of metallic elements. Chemical comparative analysis of selected dental amalgams was carried out using X-ray photoelectron spectroscopy (XPS) technique and X-ray diffraction (XRD) method. The X-ray powder diffraction measurements revealed two main phases for measured amalgams: γ1-(Ag2Hg3) and η'-(Cu6Sn5). The amount of mercury obtained by the XPS method was lower than the value quoted in the manufacturer's literature, which suggested evaporation of mercury under the UHV conditions. A linear decrease of oxygen and carbon contamination with the growing amount of Cu and Ag was observed. The XPS analysis showed that a high Sn concentration caused less resistance to oxidation. Some of the amalgams contained some extra elements, such as Bi, In, and Zn. All samples contained lead in metallic state and oxides. The amount of Ag, Cu, Sn ingredients determines the main properties of high copper amalgams and plays an important role in mercury evaporation. High tin concentration combined with the presence of smaller amounts of silver and copper (high Sn/Ag ratio) may influence the increase of mercury vaporization.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 398, Issues 1â2, 2 August 2005, Pages 276-282
Journal: Journal of Alloys and Compounds - Volume 398, Issues 1â2, 2 August 2005, Pages 276-282
نویسندگان
E. Talik, R. Babiarz-Zdyb, A. Dziedzic,