کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9804116 1516478 2005 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influences of Ni addition on the structures and electrochemical properties of La0.7Mg0.3Ni2.65+xCo0.75Mn0.1 (x = 0.0-0.5) hydrogen storage alloys
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Influences of Ni addition on the structures and electrochemical properties of La0.7Mg0.3Ni2.65+xCo0.75Mn0.1 (x = 0.0-0.5) hydrogen storage alloys
چکیده انگلیسی
In this paper, the effects of Ni addition on the structure, hydrogen storage and electrochemical properties of the La0.7Mg0.3Ni2.65+xMn0.1Co0.75 (x = 0-0.5) hydrogen storage alloys were studied systematically. The structural investigation shows that all the alloys mainly consist of the (La, Mg)Ni3 phase and the LaNi5 phase, and the abundance of the (La, Mg)Ni3 phase and the LaNi5 phase was relatively changed with increasing Ni content. Pressure-composition isotherms (P-C-T) indicate that, with increasing Ni content, the maximum hydrogen storage capacity and the hysteresis for hydrogen absorption/desorption decrease, but the plateau pressure increases. Electrochemical studies show that the maximum discharge capacity decreases from 395.1 (x = 0) to 313.8 mAh/g (x = 0.5). With increasing Ni content, the cyclic stability of alloy electrodes was not effectively improved. While x increases from 0 to 0.4, the electrochemical kinetic properties of the alloy electrodes were markedly improved due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 389, Issues 1–2, 8 March 2005, Pages 281-289
نویسندگان
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