Theory of thermal expansivity and bulk modulus

The expression for thermal expansivity and bulk modulus, claimed by Shanker et al. to be new [Physica B 233 (1977) 78; 245 (1998) 190; J. Phys. Chem. Solids 59 (1998) 197] are compared with the theory of high pressure-high temperature reported by Kumar and coworkers. It is concluded that the Shanker formulation and the relations based on this are equal to the approach of Kumar et al. up to second order.