کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9837547 1525279 2005 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrical properties of lead borosilicate glasses
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Electrical properties of lead borosilicate glasses
چکیده انگلیسی
DC electrical conductivity, σ, density, D, and molar volume, Vm, of xSiO2-(50−x)PbO-50B2O3 glasses have been studied. The results suggested that the modifier part of PbO is associated with the borate network as well as the silicate one. The activation energy for conduction, W, was found to depend predominantly on the mobility of charge carriers while the pre-exponential factor of the DC conductivity, σ0, depends predominantly on the charge carrier concentration. Each of ln σ0, W and the conductivity at certain temperature showed drastic changes at 5 mol% SiO2. The density of these glasses has been decreased continuously upon increasing SiO2 at the expense of PbO content, although the molar volume becomes nearly constant up to 10 mol% SiO2. The mobility of Pb2+ ions in silicate is larger than that in borate network.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volume 364, Issues 1–4, 15 July 2005, Pages 190-198
نویسندگان
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