کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10140638 | 1646036 | 2018 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Production of high-octane gasoline via hydrodeoxygenation of sorbitol over palladium-based bimetallic catalysts
ترجمه فارسی عنوان
تولید بنزین اکتان بالا با استفاده از هیدروژن اکسید شدن سوربیتول بر کاتالیزورهای دوار فلزی مبتنی بر پالادیوم
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
A methodology for the synthesis of gasoline-range fuels from carbon neutral resources is introduced. Sorbitol, a sugar-based compound, was employed as a raw material because the compound is readily obtained from cellulose. Gasoline-range hydrocarbons were produced via hydrodeoxygenation (HDO) on zirconium phosphate-supported Pd-bimetallic (PtâPd, RuâPd, NiâPd, FeâPd, CoâPd, WâPd) catalysts. Among the tested catalysts, the bimetallic WâPd/ZrP catalyst exhibited the highest yield of gasoline products, peaking at â¼70%. However, with the bimetallic FeâPd and CoâPd catalysts, high-octane gasoline products were made (research octane number (RON) of the products was higher than 100). The FeâPd catalyst also showed the highest initial activity for the HDO of sorbitol. This study demonstrates that HDO in the Pd-system is a promising option to produce high-quality gasoline-range hydrocarbons from lignocellulosic biomass.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Management - Volume 227, 1 December 2018, Pages 329-334
Journal: Journal of Environmental Management - Volume 227, 1 December 2018, Pages 329-334
نویسندگان
Eilhann E. Kwon, Yong Tae Kim, Hyung Ju Kim, Kun-Yi Andrew Lin, Ki-Hyun Kim, Jechan Lee, George W. Huber,