کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10141496 | 1646072 | 2018 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solvatochromism of a highly conjugated novel donor-Ï-acceptor dipolar fluorescent probe and its application in surface-energy transfer with gold nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel highly conjugated donor-Ï-acceptor (D-Ï-A) fluorescent probe 4-((1E,3E)-4-(4-(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)phenyl)buta-1,3-dienyl)-N,N-dimethylbenzenamine (3TVPO) is synthesized using a Wittig reaction and characterized by 1H, 13C NMR, FT-IR spectroscopy and high-resolution mass spectrometry (HR-MS). The photophysical properties have been studied to understand the intramolecular charge-transfer (ICT) character of the compound. The solvatochromism of 3TVPO has been explored in polar protic/aprotic/weakly polar solvents. Various solvent correlation techniques such as Lippert-Mataga, Bilot-Kawski, Kawski-Chamma-Viallet, Bakhshiev, and Reichardt methods were employed to estimate the singlet ground- and excited-state dipole moment and are compared and discussed with those obtained computationally. The specific and non-specific solute-solvent interactions were analyzed using Kamlet-Taft and Catalán solvent parameters by means of a multiple-linear-regressions (MLR) method. In addition, surface-energy transfer (SET) has been studied using this optoelectronically important 3TVPO molecule as efficient donor and gold nanoparticles (Au MNPs) as excellent acceptors employing steady-state and time-resolved spectroscopic techniques. The size- and distance-dependent SET between 3TVPO and Au MNPs was explored. It is demonstrated that the quenching efficiency increases as the size of Au MNPs increases from 40 to 53â¯nm. The super-quenching effect and nonradiative energy transfer were analyzed using Stern-Volmer plots. The impact of the present investigation about the super-quenching effect of the Au MNPs can be exploited for biosensing applications owing to its acute sensitivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 271, 1 December 2018, Pages 118-127
Journal: Journal of Molecular Liquids - Volume 271, 1 December 2018, Pages 118-127
نویسندگان
G.H. Pujar, Narahari Deshapande, Imtiyaz Ahmed M. Khazi, Sanjeev R. Inamdar,