کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10246862 | 48551 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Transition metal Schiff-base complexes chemically anchored on Y-zeolite: their preparation and catalytic epoxidation of 1-octene in the suspension and phase boundary systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Transition metal Schiff-base complexes chemically anchored on Y-zeolite: their preparation and catalytic epoxidation of 1-octene in the suspension and phase boundary systems Transition metal Schiff-base complexes chemically anchored on Y-zeolite: their preparation and catalytic epoxidation of 1-octene in the suspension and phase boundary systems](/preview/png/10246862.png)
چکیده انگلیسی
The Schiff-base (APTSsal) transition metal complexes anchored on Y-zeolite were prepared and characterized. The anchored Schiff-bases imposed stable planar coordination sphere on the metal ions, allowing epoxidation of 1-octene in the axial position in the presence of molecular oxygen. The epoxidation of 1-octene was also achieved by employing the partly modified Y-zeolite with n-octadecyltrichlorosilane (OTS) Schiff-base complexes in the presence of 30% H2O2 under a phase-boundary system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 225, Issue 2, 18 January 2005, Pages 181-188
Journal: Journal of Molecular Catalysis A: Chemical - Volume 225, Issue 2, 18 January 2005, Pages 181-188
نویسندگان
Sahar I. Mostafa, Shigeru Ikeda, Bunsho Ohtani,