کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10269084 459718 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical properties of palladium(II) trans- and cis-diglycinate complexes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrochemical properties of palladium(II) trans- and cis-diglycinate complexes
چکیده انگلیسی
The kinetics of trans-cis-isomerization of palladium(II) diglycinate complexes have been studied by the spectrophotometric and potentiometric methods. The reaction of transition of trans-[Pd(Gly)2] to cis-[Pd(Gly)2] is described by a first-order equation. The half-life of the trans-isomer [Pd(Gly)2] and the rate constant of the reaction of its transition to cis-isomeric structure have been determined. A mechanism of transformation of trans-[Pd(Gly)2] into cis-[Pd(Gly)2] is proposed. The spectral characteristics and electrochemical parameters of palladium(II) trans- and cis-diglycinate complexes have been determined. The mechanism of electroreduction of palladium(II) from glycinate electrolyte containing no excess free ligand has been elucidated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 5, 1 February 2011, Pages 2110-2115
نویسندگان
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