کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10407005 892830 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of annealing temperature on the phase composition and optical properties of CuInS2 films
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
Influence of annealing temperature on the phase composition and optical properties of CuInS2 films
چکیده انگلیسی
We studied the growth of CuInS2 thin films by single-source evaporation of CuInS2 powder in a high-vacuum system with a base pressure of 10−3 Pa. After evaporation, the films were annealed in a sulfur atmosphere at temperatures from 200 to 500 °C for 1 h. XRD curves and Raman spectra of the films demonstrated that chalcopyrite CuInS2 was the major crystalline phase. The morphology of CuxS exhibited a star-like structure, which we report for the first time. The phase composition and optical properties of our polycrystalline thin films were effectively modified by annealing in S. For films annealed at 200 and 350 °C, a secondary CuIn11S17 phase appeared, which may be related to solid-state reaction in the S atmosphere. This secondary CuIn11S17 phase has not been widely reported in previous studies. After annealing at 500 °C, only a chalcopyrite phase was detected, with bandgap energy of 1.46 eV, which is nearly identical to the optimal bandgap energy (1.5 eV) of single-crystal CuInS2. This indicates that the composition of the CuInS2 film annealed at 500 °C was nearly stoichiometric. The bandgap of the samples first increased and then decreased with increasing annealing temperature, which may be attributed to an increase in grain size, the secondary CuIn11S17 phase, and deviation from stoichiometry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science in Semiconductor Processing - Volume 16, Issue 6, December 2013, Pages 1472-1477
نویسندگان
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