کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10528754 960727 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical determination of 2,4-D at a mercury electrode
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Electrochemical determination of 2,4-D at a mercury electrode
چکیده انگلیسی
An indirect electrochemical determination of 2,4-dichlorophenoxyacetic acid (2,4-D), has been presented. The method is based on the adsorption and desorption of 2,4-D on mercury electrode. Also, the electrochemical behavior of 2,4-D in aqueous solutions at different pH values and different 2,4-D concentrations were studied. A simple and rapid method has been developed for its extraction from water and soil. The subsequent determination was carried out by a tensammetric method. Three calibration curves could be obtained from different parts of voltammogram. Under the optimum conditions (pH = 2.3; Eacc = −1100 mV; tacc = 60 s; alternative current mode; ν = 40 mV s−1; pulse height = 20 mV; modulation frequency = 60 Hz; phase angle = 90°) the limit of detection was 50 μg L−1. The proposed method was applied to the determination of 2,4-D in real samples such as soil and water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 530, Issue 1, 7 February 2005, Pages 69-74
نویسندگان
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