کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10560080 | 969703 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Determination of trace mercury by solid substrate room temperature phosphorescence quenching method based on lead carboxymethyl cellulose (Pb(CMC)2) particles containing luminescent salicyl fluorones molecules
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Determination of trace mercury by solid substrate room temperature phosphorescence quenching method based on lead carboxymethyl cellulose (Pb(CMC)2) particles containing luminescent salicyl fluorones molecules Determination of trace mercury by solid substrate room temperature phosphorescence quenching method based on lead carboxymethyl cellulose (Pb(CMC)2) particles containing luminescent salicyl fluorones molecules](/preview/png/10560080.png)
چکیده انگلیسی
Luminescent particles of lead carboxymethyl cellulose (Pb(CMC)2), which contains salicyl fluorones (THBF), Pb(CMC)2-THBF, were synthesized by sol-gel method. Pb(CMC)2-THBF can emit intense and stable solid substrate room temperature phosphorescence (SS-RTP) on filter paper. EDTA can chelate the Pb2+ in Pb(CMC)2-THBF, causing it decompose into aqueous soluble components PbY2â, CMCâ and THBF, and these components can react with Hg2+ to form (CMC)2Hg-THBF, causing decrease of phosphorescence intensity. Based on the facts above, a new method for the determination of trace mercury by SS-RTP quenching method was established. The linear range of this method is 2.0-40.0 fg spotâ1 (5.0-100.0 pg mlâ1) of Hg2+, with a detection limit (LD) of 0.26 fg spotâ1, and the regression equation of working curve is ÎIp=13.02+1.165mHg2+ (fg spotâ1, 0.4 μl spotâ1), r = 0.9994. This method has been applied to the determination of trace mercury in water sample with satisfactory results. The mechanism of SS-RTP emission is also discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 65, Issue 2, 30 January 2005, Pages 501-504
Journal: Talanta - Volume 65, Issue 2, 30 January 2005, Pages 501-504
نویسندگان
Jia-Ming Liu, Ai-Hong Wu, Huan-Huan Xu, Qing-Hua Wang, Long-Di Li, Guo-Hui Zhu,