کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10569597 | 974158 | 2013 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structure and electronic properties of Pd(III) complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Structure and electronic properties of Pd(III) complexes Structure and electronic properties of Pd(III) complexes](/preview/png/10569597.png)
چکیده انگلیسی
⺠Despite the rich chemistry of palladium in the 0, +2, and +4 oxidation states, Pd(III) complexes are less common. ⺠Pd complexes are among the most widely used catalysts in organic chemistry, yet organometallic Pd(III) complexes have only been reported starting in 2006. ⺠A number of Pd(III) complexes have been proposed recently as catalytic intermediates in CH functionalization, CC bond formation, and radical reactions. ⺠This review provides an overview of the synthesis and spectroscopic characterization of mononuclear and dinuclear Pd(III) complexes. ⺠A detailed understanding of the steric and electronic properties of Pd(III) complexes should provide insight for the development of novel catalysts for various redox reactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 257, Issue 2, 15 January 2013, Pages 299-314
Journal: Coordination Chemistry Reviews - Volume 257, Issue 2, 15 January 2013, Pages 299-314
نویسندگان
Liviu M. Mirica, Julia R. Khusnutdinova,