کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10609257 | 984560 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of pentafluorophenyl(meth)acrylate polymers: New precursor polymers for the synthesis of multifunctional materials
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Pentafluorophenyl acrylate and -methacrylate were polymerized using AIBN as a thermal initiator. The obtained polymers were soluble polymeric active esters that could be used for the preparation of multifunctional polymers. The reactivity of poly(pentafluorophenylacrylate) and poly(pentafluorophenylmethacrylate) towards primary and secondary amines, as well as alcohols was investigated in a quantitative way. Both poly(active esters) reacted satisfactorily with aliphatic primary and secondary amines but only low conversion was found in the case of aromatic amines. Conversions of only 30% were reached when poly(pentafluorophenylacrylate) was treated with one equivalent of alcohol under base catalysis. In time resolved FT-IR studies the rate constants of the polymer analogous reactions were determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 41, Issue 7, July 2005, Pages 1569-1575
Journal: European Polymer Journal - Volume 41, Issue 7, July 2005, Pages 1569-1575
نویسندگان
Marc Eberhardt, Ralf Mruk, Rudolf Zentel, Patrick Théato,