کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10609327 | 984569 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modification of epoxy-novolac resins with polysiloxane containing nitrile functional groups: synthesis and characterization
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Synthesis of the statistical epoxidized polycyanopropylmethylsiloxane-co-polydimethylsiloxanes (PCPMS-co-PDMS) has been demonstrated. The modified polysiloxanes were prepared via a two-step method; (1) the ring-opening polymerization of octamethylcyclotetrasiloxane (D4) and tetramethylcyclotetrasiloxane (D4H), (2) hydrosilylation reaction of the polysiloxane prepolymers with allyl cyanide and allyl glycidyl ether. Molar ratios of D4H and D4 were varied to produce the modified polysiloxanes with differences in polarity. 1H-NMR, 29Si-NMR, 13C-NMR and FTIR were used to monitor the formation of the modified polysiloxanes and DSC was used to study their thermal behaviors (Tg, â118 to â68 °C). The use of the modified polysiloxanes as an elastomeric component in epoxy-novolac networks was also investigated. TEM and their transition temperatures suggested that the epoxy-novolac networks with high content of PDMS modifiers exhibited microphase separation. The fracture toughness properties of the networks with the polysiloxane modifiers were improved over the controls without polysiloxanes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 41, Issue 5, May 2005, Pages 1043-1052
Journal: European Polymer Journal - Volume 41, Issue 5, May 2005, Pages 1043-1052
نویسندگان
Metha Rutnakornpituk,