کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1163113 | 1490929 | 2016 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Printing graphene-carbon nanotube-ionic liquid gel on graphene paper: Towards flexible electrodes with efficient loading of PtAu alloy nanoparticles for electrochemical sensing of blood glucose Printing graphene-carbon nanotube-ionic liquid gel on graphene paper: Towards flexible electrodes with efficient loading of PtAu alloy nanoparticles for electrochemical sensing of blood glucose](/preview/png/1163113.png)
• Self-assembly of graphene nanosheets and carbon nanotubes into three-dimensional porous nanohybrid material.
• Printing of graphene–carbon nanotube nanohybrid material on freestanding graphene paper using ionic liquids as the binder.
• Ultrasonic-electrodeposition of PtAu alloy nanoparticles on flexible graphene-based nanohybrid paper electrode.
• Nonenzymatic electrochemical sensing of glucose in human blood samples.
The increasing demands for portable, wearable, and implantable sensing devices have stimulated growing interest in innovative electrode materials. In this work, we have demonstrated that printing a conductive ink formulated by blending three-dimensional (3D) porous graphene–carbon nanotube (CNT) assembly with ionic liquid (IL) on two-dimensional (2D) graphene paper (GP), leads to a freestanding GP supported graphene–CNT–IL nanocomposite (graphene–CNT–IL/GP). The incorporation of highly conductive CNTs into graphene assembly effectively increases its surface area and improves its electrical and mechanical properties. The graphene–CNT–IL/GP, as freestanding and flexible substrates, allows for efficient loading of PtAu alloy nanoparticles by means of ultrasonic-electrochemical deposition. Owing to the synergistic effect of PtAu alloy nanoparticles, 3D porous graphene–CNT scaffold, IL binder and 2D flexible GP substrate, the resultant lightweight nanohybrid paper electrode exhibits excellent sensing performances in nonenzymatic electrochemical detection of glucose in terms of sensitivity, selectivity, reproducibility and mechanical properties.
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Journal: Analytica Chimica Acta - Volume 903, 15 January 2016, Pages 61–68