کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1165521 1491069 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Paper-based solid-state electrochemiluminescence sensor using poly(sodium 4-styrenesulfonate) functionalized graphene/nafion composite film
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Paper-based solid-state electrochemiluminescence sensor using poly(sodium 4-styrenesulfonate) functionalized graphene/nafion composite film
چکیده انگلیسی

Herein, highly efficient solid-state ECL sensor was introduced for the first time onto the screen printed electrodes of the paper-based chips (PCs) based on the composite film of poly(sodium 4-styrenesulfonate) functionalized graphene (PSSG) and Nafion. Attributed to the cooperative characteristics of both PSS and graphene, PSSG ensured both effective Ru(bpy)32+ immobilization and fast electron transfer of Ru(bpy)32+ in the composite film. The ECL behaviors at the developed sensor were investigated using tripropylamine as a representative analyte and low detection limit (S N−1 = 3) of 5.0 nM was obtained. It also exhibited more excellent reproducibility (relative standard deviations of 0.63% for continuous 45 cycles) and long-term stability (∼80% of its initial ECL intensity could be retained over 3 months). More importantly, assisted by the developed ECL sensor, discrimination of 1.0 nM single-nucleotide mismatch in human urine matrix could be realized on the PCs for the first attempt. Thus, the developed sensor was confirmed with the advantages of highly sensitivity, long-term stability, simplicity, low cost, disposability, high efficiency and potential applicability.

Figure optionsDownload as PowerPoint slideHighlights
► Solid-state ECL sensor was introduced into paper-based chips for the first time.
► Composite film of functionalized graphene/Nafion was used for sensor fabrication.
► Excellent reproducibility and long-term stability were obtained for the sensor.
► Single-base mismatch detection in human urine was realized on paper-based chips.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 763, 6 February 2013, Pages 20–27
نویسندگان
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