کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1168199 960579 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Capillary electrochromatography with contactless conductivity detection for the determination of some inorganic and organic cations using monolithic octadecylsilica columns
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Capillary electrochromatography with contactless conductivity detection for the determination of some inorganic and organic cations using monolithic octadecylsilica columns
چکیده انگلیسی

A fast separation of alkali and alkaline earth metal cations and ammonium was carried out by capillary electrochromatography on monolithic octadecylsilica columns of 15 cm length and 100 μm inner diameter using water/methanol mixtures containing acetic acid as mobile phase. On-column contactless conductivity detection was used for quantification of these non-UV-absorbing species. The method was also extended successfully to the determination of small amines as well as of amino acids, and the separation selectivity was optimized by varying the composition of the mobile phase. Detection limits of about 1 μM were possible for the inorganic cations as well as for the small amines, while the amino acids could be quantified down to about 10 μM. The separation of 12 amino acids was achieved in the relatively short time of 10 min.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 653, Issue 2, 27 October 2009, Pages 228–233
نویسندگان
, , ,