کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1169639 | 960644 | 2009 | 6 صفحه PDF | دانلود رایگان |

Metallic nanoparticles of rhodium were prepared by using the newly synthesized N,N-bis-succinamide-based dendrimer as stabilizers. The Rh nanoparticles were spherical shaped with a particle size of ∼2 nm. The dendrimer Rh-encapsulated nanoparticles (Rh-DENs) were immobilized on glassy carbon electrode (GCE) and their electrocatalytic activity towards hydrogen peroxide reduction was investigated using cyclic voltammetry and chronoamperometry. The Rh-DENs modified GCE showed excellent electrocatalytic activity for hydrogen peroxide reduction reactions. The steady-state cathodic current response of the modified electrode at −0.3 V (vs SCE) in phosphate buffer (pH 7.0) showed a linear response to hydrogen peroxide concentration ranging from 8 to 30 μM with a detection limit and sensitivity of 5 μM and 0.03103 × 10−6 A μM−1, respectively.
Journal: Analytica Chimica Acta - Volume 632, Issue 1, 19 January 2009, Pages 63–68