کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1171215 1491172 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Use of sequential injection analysis to construct an electronic-tongue: Application to multidetermination employing the transient response of a potentiometric sensor array
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Use of sequential injection analysis to construct an electronic-tongue: Application to multidetermination employing the transient response of a potentiometric sensor array
چکیده انگلیسی

An electronic tongue based on the transient response of an array of non-specific-response potentiometric sensors was developed. A sequential injection analysis (SIA) system was used in order to automate its training and operation. The use of the transient recording entails the dynamic nature of the sensor's response, which can be of high information content, of primary ions and also of interfering ions; these may better discriminated if the kinetic resolution is added. This work presents the extraction of significant information contained in the transient response of a sensor array formed by five all-solid-state potentiometric sensors. The tool employed was the Fourier transform, from which a number of coefficients were fed into an artificial neural network (ANN) model, used to perform a quantitative multidetermination. The studied case was the analysis of mixtures of calcium, sodium and potassium. Obtained performance is compared with the more traditional automated electronic tongue using final steady-state potentials.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 600, Issues 1–2, 26 September 2007, Pages 97–104
نویسندگان
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