کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1172597 960791 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Simultaneous spectrophotometric determination of iron, nickel and cobalt in micellar media by using direct orthogonal signal correction-partial least squares method
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Simultaneous spectrophotometric determination of iron, nickel and cobalt in micellar media by using direct orthogonal signal correction-partial least squares method
چکیده انگلیسی

A very simple and selective spectrophotometric method for simultaneous determination of iron(II), nickel(II) and cobalt(II) based on formation of their complexes with 1-(2-pyridylazo)-2-naphtol (PAN) in micellar media is described. Although the complexes of Fe(II), Ni(II) and Co(II) with reagent show a spectral overlap, they have been simultaneously determined by partial least squares (PLS) with and without preprocessing step using direct orthogonal signal correction (DOSC). The linear range was 0.30–4.50 μg ml−1 for Co(II), 0.20–3.00 μg ml−1 for Ni(II) and 0.30–5.00 μg ml−1 for Fe(II). The results obtained by the PLS and DOSC–PLS were statistically compared. Interference effects of common anions and cations were studied and the proposed method was also applied satisfactorily to the determination of Fe(II), Ni(II) and Co(II) in synthetic samples.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 556, Issue 1, 18 January 2006, Pages 247–254
نویسندگان
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