کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1172597 | 960791 | 2006 | 8 صفحه PDF | دانلود رایگان |

A very simple and selective spectrophotometric method for simultaneous determination of iron(II), nickel(II) and cobalt(II) based on formation of their complexes with 1-(2-pyridylazo)-2-naphtol (PAN) in micellar media is described. Although the complexes of Fe(II), Ni(II) and Co(II) with reagent show a spectral overlap, they have been simultaneously determined by partial least squares (PLS) with and without preprocessing step using direct orthogonal signal correction (DOSC). The linear range was 0.30–4.50 μg ml−1 for Co(II), 0.20–3.00 μg ml−1 for Ni(II) and 0.30–5.00 μg ml−1 for Fe(II). The results obtained by the PLS and DOSC–PLS were statistically compared. Interference effects of common anions and cations were studied and the proposed method was also applied satisfactorily to the determination of Fe(II), Ni(II) and Co(II) in synthetic samples.
Journal: Analytica Chimica Acta - Volume 556, Issue 1, 18 January 2006, Pages 247–254