Expert system for monitoring the tributyltin content in inland water samples

In this study we discuss an attempt to build an expert system that can support decision making by analytical chemists regarding the presence of tributyltin (TBT) in inland Polish water samples in detail. It is possible to conclude with at least a 0.93 probability that a sample is free of TBT using the expert system that was constructed (if a sample is analyzed in accordance with the European norm PN-EN ISO 17353:2006). This idea, which is based on the efficient use of the information that is stored in a chromatographic database, can easily be extended to monitor other priority substances in water samples. Our on-going research, which is focused on octylphenols in water samples, has provided very encouraging results and additionally supports this hypothesis. The proposed framework can also be attractive to other testing laboratories that have a similar scope of expertise and follow the same analytical protocols. Moreover, as a natural consequence of our research further efforts should lead to the development of a ready-to-use product that would offer testing laboratories validated chromatographic libraries along with the expert system(s) with the possibility of upgrading them with respect to an increasing pool of analyzed samples. Such a solution when implemented in a testing laboratory environment may have a wide economic impact on its further functioning and increase throughput efficiency, especially in a case in which monitoring priority substances in water is a major concern.