کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1196769 1492973 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pyrolysis/gas chromatography/mass spectrometry analysis of 5,10,15,20-tetraphenyl-21H,23H-porphyrin and some of its derivatives
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Pyrolysis/gas chromatography/mass spectrometry analysis of 5,10,15,20-tetraphenyl-21H,23H-porphyrin and some of its derivatives
چکیده انگلیسی

A coupled on-line pyrolysis/gas chromatography/mass spectrometry technique (Py/GC/MS) was applied to identify products of pyrolysis of 5,10,15,20-tetraphenyl-21H,23H-porphyrin (1a) and its methyl and hydroxyl substituted derivatives (1b and 1c). The mass spectra of some important pyrolitic products are presented and mass fragmentation of this type compounds is discussed. From the investigation it can be concluded that the direction of the main thermal (pyrolytic) reactions is similar for all compounds studied: namely breaking of the porphyrin macrocycle followed by splitting of molecule fragments containing one, two or three pyrrole and/or benzene rings. The products of pyrolysis can be simply correlated with the structures of porphyrins.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Analytical and Applied Pyrolysis - Volume 104, November 2013, Pages 111–116
نویسندگان
, , , ,