Py/GC/MS characterisation of naturally and artificially aged inks and papers

A set of inks was analyzed using Py/GC/MS technique. They were prepared following some ancient Armenian recipes and then analyzed after being dried in air to obtain solid samples. A simple analytical procedure was adopted which excludes any treatment of the samples and consists in introducing the solid sample directly into the injector of the furnace pyrolyzer. Inks were also written on whatman paper by calamum and analyses of papers containing ink were carried out. A real sample analysis was reported. Comparing the pyrograms it was possible to discriminate fragments derived from ink, from that formed by the decomposition of paper by the influence of ink. In order to understand the origin of the fragments formed during the pyrolysis of inks the standard compounds used to prepare them were carried out, too.