کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1204970 | 1493714 | 2008 | 5 صفحه PDF | دانلود رایگان |
Partitioned dispersive liquid–liquid microextraction (PDLLME) efficiency was demonstrated for the extraction of polar organic compounds (chlorophenoxyacetic acids) prior to high performance liquid chromatography (HPLC). The method was based on the formation of tiny droplets of an organic extractant in an aqueous sample (river water) by injecting a mixture of a water-immiscible organic solvent [tetrachloroethylene (TCE)] as extractant dissolved in a water-miscible organic dispersive solvent [tetrahydrofuran (THF)]. Based on their partition coefficients, polar compounds were extracted into the dispersed TCE droplets as well as into THF. Different parameters affecting the extraction efficiency were evaluated and precision, linearity, detection limit and an enrichment factor were determined.
Journal: Journal of Chromatography A - Volume 1207, Issues 1–2, 17 October 2008, Pages 24–28