کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1204989 1493714 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Size-exclusion chromatography with organic carbon detection using a mass spectrometer
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Size-exclusion chromatography with organic carbon detection using a mass spectrometer
چکیده انگلیسی

A novel organic carbon detector for size-exclusion chromatography (SEC) is described. The instrument uses the conventional UV-persulfate oxidation method to convert organic carbon to CO2, which is then detected using a mass spectrometer. This system, using the mass spectrometer, had lower limits of detection (LOD) and limits of quantification (LOQ) than a previously described system using a Fourier transform infrared (FTIR) spectroscopy ‘lightpipe’ detector (i.e. when quantification was based on calibration using phthalate standards). When used to analyse natural organic matter (NOM) in water, it also had a superior signal-to-noise ratio to the previously described system. The use of a mass spectrometer to detect organic carbon (as CO2) enables the possibility of further characterisation of NOM by measuring the stable carbon isotope ratios of the various molecular size fractions of organic carbon, as obtained by SEC.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1207, Issues 1–2, 17 October 2008, Pages 186–189
نویسندگان
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