کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1208731 965315 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Supercritical fluid extraction of macrocyclic lactone mycotoxins in maize flour samples for rapid amperometric screening and alternative liquid chromatographic method for confirmation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Supercritical fluid extraction of macrocyclic lactone mycotoxins in maize flour samples for rapid amperometric screening and alternative liquid chromatographic method for confirmation
چکیده انگلیسی

A rapid and simple method for the direct screening of macrocyclic lactone mycotoxins (zearalenone, ZON; α-zearalenol, α-ZOL; and β-zearalenol, β-ZOL) in maize flour samples is proposed. The sample screening method comprises supercritical fluid extraction (SFE) and clean-up on Florisil adsorption cartridge of the selected toxic compounds, followed by continuous flow electrochemical detection. Those samples for which the total concentration is close to or above the threshold limit established by legislation (0.200 mg kg−1) are subjected to preconcentration on C18 chromatographic material and liquid chromatographic separation for confirmation purposes. This confirmation method allows the determination of ZON, α-ZOL and β-ZOL in the range between 30 and 300 μg kg−1, with a average relative standard deviation lower than 5.2 in all cases.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1177, Issue 1, 4 January 2008, Pages 50–57
نویسندگان
, ,