کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1209146 | 965330 | 2007 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Measurement uncertainty arising from trueness of the analysis of two endocrine disruptors and their metabolites in environmental samples
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, a preconcentration method for the simultaneous determination of the endocrine disrupting chemicals (EDCs), diuron (1-(3,4-dichlorophenyl)-3,3-dimethylurea), and linuron (3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea), as well as their metabolites DCPU (1-(3,4-dichlorophenyl) urea), DCPMU (1-(3,4-dichlorophenyl)-3-methylurea) and 3,4-DCA (3,4-dichloroaniline), present in natural waters was optimized and validated. Water was subjected to solid-phase extraction (SPE) and the influence of several experimental variables affecting the extraction efficiency of the target analytes was studied, including the sorbent material, elution solvents, pH and breakthrough volume, as well as some solution parameters that is, ionic strength and organic matter content. A high-performance liquid chromatography system coupled to UV-diode array detector (DAD) was used for the target analytes quantification at the optimum conditions described in Part I. The fully nested experimental design, adapted to the new experimental parameters, was used to study the measurement uncertainty arising from trueness by estimating proportional bias (in terms of recovery). The overall recoveries of the target analytes were in the range of 71.6-90.2%, except 3,4-DCA for which a low overall recovery of 51.4% was obtained. The analytical procedure was shown to be linear over the studied range of concentration (25-400Â ng/l), exhibiting satisfactory repeatability and reaching limits of detection in the 1.3-11.2Â ng/l range for all, quite different in nature, water types. The SPE method was further applied for the determination of the selected EDCs and their metabolites in water samples taken from selected study stations in the region of Epirus (N.W. Greece) corresponding to the sediment samples locations (Part I).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1146, Issue 2, 6 April 2007, Pages 148-156
Journal: Journal of Chromatography A - Volume 1146, Issue 2, 6 April 2007, Pages 148-156
نویسندگان
V.I. Boti, V.A. Sakkas, T.A. Albanis,