کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1211685 1493778 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Development and application of a sol–gel immunosorbent-based method for the determination of isoproturon in surface water
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Development and application of a sol–gel immunosorbent-based method for the determination of isoproturon in surface water
چکیده انگلیسی

An immunosorbent was fabricated by encapsulation of monoclonal anti-isoproturon antibodies in sol–gel matrix. The immunosorbent-based loading, rinsing and eluting processes were optimized. Based on these optimizations, the sol–gel immunosorbent (SG-IS) selectively extracted isoproturon from an artificial mixture of 68 pesticides. In addition to this high selectivity, the SG-IS proved to be reusable. The SG-IS was combined with liquid chromatography–tandem mass spectrometry (LC–MS–MS) to determine isoproturon in surface water, and the linear range was up to 2.2 μg/l with correlation coefficient higher than 0.99 and relative standard deviation (RSD) lower than 5% (n = 8). The limit of quantitation (LOQ) for 25-ml surface water sample was 5 ng/l.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1102, Issues 1–2, 13 January 2006, Pages 84–90
نویسندگان
, , , , ,