کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1213809 1494123 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Analytical methodology for the study of endosulfan bioremediation under controlled conditions with white rot fungi
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Analytical methodology for the study of endosulfan bioremediation under controlled conditions with white rot fungi
چکیده انگلیسی

A general procedure to study the biodegradation of endosulfan under laboratory conditions by white rot fungi isolated from native sources growing in YNB (yeast nitrogen base) media with 1% of glucose is presented. The evaluation of endosulfan biodegradation as well as endosulfan sulfate, endosulfan ether and endosulfan alcohol production throughout the whole bioremedation process was performed using an original and straightforward validated analytical procedure with recoveries between 78 and 112% at all concentration levels studied except for endosulfan sulfate at 50 mg L−1 that yielded 128% and RSDs < 20%. Under the developed conditions, the basidiomycete Bjerkandera adusta was able to degrade 83% of (alpha + beta) endosulfan after 27 days, 6 mg kg−1 of endosulfan diol were determined; endosulfan ether and endosulfan sulfate were produced below 1 mg kg−1 (LOQ, limit of quantitation).


► Endosulfan dissipation/metabolites formation determined in a single analytical step.
► The validated method ensures the accurate evaluation of the bioremediation technique.
► Bjerkandera adusta showed 83% of endosulfan bioconversion after 27 days.
► The most toxic metabolite (endosulfan sulfate) was produced at a minimum level.
► Other metabolites (endosulfan diol and endosulfan ether) were detected.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography B - Volume 907, 15 October 2012, Pages 168–172
نویسندگان
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