کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1249635 | 1495999 | 2012 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improvement of “concatenated” two-dimensional correlation analysis and its new potential applications on the quantitative evaluation of the process reversibility under different perturbations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
“Concatenated” 2D correlation analysis is a powerful technique in identifying the homology or very subtle difference between two similar spectra. The basic scheme of the method is firstly to construct a possible “mirror” relationship between two original spectral data sets along the perturbation axis and then to perform the 2D correlation calculation on the joint data sets and finally to reveal the similarity or subtle difference by the appearance of the asynchronous peaks. The approach has been demonstrated to be very efficient and offers many potential applications such as the examination of process reversibility, the discrimination and classification of traditional Chinese medicines (TCM), etc. The effects of some factors on the technique, including the spectral intensity, the band shift and the data size, etc., are investigated in detail in the present study. A quantitative criterion is established by some improvements on the novel method, which may extend the application of the method to more systems. Its efficiency in the quantitative analysis of the process reversibility for the same system under different perturbations is explored in the present study.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 60, May 2012, Pages 220-225
Journal: Vibrational Spectroscopy - Volume 60, May 2012, Pages 220-225
نویسندگان
Yuqing Wu, Liping Zhang, Isao Noda,