کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1249875 1495984 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Interaction of sodium and potassium ions with PEO-PPO copolymer investigated by FTIR, Raman and NMR
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Interaction of sodium and potassium ions with PEO-PPO copolymer investigated by FTIR, Raman and NMR
چکیده انگلیسی

Many papers have reported that salt ions can exert a great influence on the self-assembly behavior of PEO-PPO copolymers in the aqueous solution. Whereas the mechanism through which salt ions influence the self-assembly behavior of PEO-PPO copolymers is unclear and the dispute is mainly focused on whether the salt ions have a direct interaction with PEO-PPO copolymers. In this paper, the interaction of sodium and potassium ions with PEO-PPO copolymer was investigated by using FTIR, Raman and 23Na NMR spectroscopy. Experimental results reveal that direct interactions between salt cations and PEO-PPO macromolecular chains indeed occur in appropriate conditions. The present work highlights the role of cations in the self-assembly process of PEO-PPO copolymer.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 75, November 2014, Pages 59–64
نویسندگان
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