کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1250090 | 970777 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Raman spectroscopy evidence of 1:1:1 complex formation during dissolution of WO3 in a melt of K2S2O7:K2SO4
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Highly inert yellow solid WO3 was found to be soluble in considerable amounts in molten K2S2O7 at elevated temperatures (â¼650 °C), if only similar molar amounts of sulfates were also present. The dissolution reaction of WO3 into a melt consisting of a 1:1 molar mixture of K2S2O7 and K2SO4 was studied in detail, and Raman spectroscopy was used to characterize the products. In combination with single crystal X-ray crystal structure determination, it was shown that a new dimeric compound, K8[{WVIO2(SO4)2}2(μ-SO4)2], was formed and its assigned Raman spectrum at room temperature is given. The WO22+ cores of the dimeric complex have their symmetrical and antisymmetrical stretching modes ν1(WO22+) and ν3(WO22+) at around 1054 (strong) and 1042 (weak), and the bending mode ν2(WO22+) at around 292 (medium intensity), respectively (positions given in cmâ1).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 42, Issue 2, 24 November 2006, Pages 346-352
Journal: Vibrational Spectroscopy - Volume 42, Issue 2, 24 November 2006, Pages 346-352
نویسندگان
Rolf W. Berg, Irene Maijó Ferré, Susan J. Cline Schäffer,