کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1272211 | 1497479 | 2014 | 9 صفحه PDF | دانلود رایگان |
• We have successfully synthesized a composite of graphite oxide, ionic liquid, and Ru: GO-IL-Ru.
• It is a good catalyst for use in the benzene hydrogenation reaction to cyclohexane.
• The catalytic activity of GO-IL-Ru was good at compounds with phenyl groups, but not at vinyl compounds.
• GO-IL-Ru maintains good activity after several cycles of hydrogenation reactions.
The manuscript herein is on the synthesis and characterization of a graphene composite abbreviated as GO-IL-Ru that is based on graphite oxide with additional functional groups of organic ionic trains. It contains Ru at 1.61 wt% level (by ICP-OES). We have used GO-IL-Ru as catalyst in both the hydrogenation reactions and the transfer hydrogenation reactions. The catalytic activity of GO-IL-Ru was good at compounds with phenyl groups, but not at those containing electronegative substituents or heterocyclic rings.
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 30, 13 October 2014, Pages 17492–17500