Ultrasonic spray pyrolysis synthesis of Ag/TiO2 nanocomposite photocatalysts for simultaneous H2 production and CO2 reduction

Simultaneous photocatalytic hydrogen production and CO2 reduction (to form CO and CH4) from water using methanol as a hole scavenger were investigated using silver-modified TiO2 (Ag/TiO2) nanocomposite catalysts. A simple ultrasonic spray pyrolysis (SP) method was used to prepare mesoporous Ag/TiO2 composite particles using TiO2 (P25) and AgNO3 as the precursors. The material properties and photocatalytic activities were compared with those prepared by a conventional wet-impregnation (WI) method. It was found that the samples prepared by the SP method had a larger specific surface area and a better dispersion of Ag nanoparticles on TiO2 than those prepared by the WI method, and as a result, the SP samples showed much higher photocatalytic activities toward H2 production and CO2 reduction. The optimal Ag concentration on TiO2 was found to be 2 wt%. The H2 production rate of the 2% Ag/TiO2–SP sample exhibited a six-fold enhancement compared with the 2% Ag/TiO2–WI sample and a sixty-fold enhancement compared with bare TiO2. The molar ratio of H2 and CO in the final products can be tuned in the range from 2 to 10 by varying the reaction gas composition, suggesting a viable way of producing syngas (a mixture of H2 and CO) from CO2 and water using the prepared Ag/TiO2 catalysts with energy input from the sun.

Graphical AbstractFigure optionsDownload as PowerPoint slideHighlights
► Ag/TiO2 are prepared for photocatalytic H2 production and CO2 reduction with water.
► Ultrasonic spray pyrolysis preparation method is superior to wet-impregnation.
► 2% Ag/TiO2–SP mesoporous microspheres demonstrate the highest activity.
► H2 production and CO2 reduction processes compete for electrons and protons.
► Syngas is produced with a H2/CO ratio of 2:1.