کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1278816 1497630 2009 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Production of hydrogen via steam reforming of biofuels on Ni/CeO2–Al2O3 catalysts promoted by noble metals
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Production of hydrogen via steam reforming of biofuels on Ni/CeO2–Al2O3 catalysts promoted by noble metals
چکیده انگلیسی

The catalytic activity of Ni/CeO2–Al2O3 catalysts modified with noble metals (Pt, Ir, Pd and Ru) was investigated for the steam reform of ethanol and glycerol. The catalysts were characterized by the following techniques: Energy-dispersive X-ray, BET, X-ray diffraction, temperature-programmed reduction, UV–vis diffuse reflectance spectroscopy and X-ray absorption near edge structure (XANES). The results showed that the formation of inactive nickel aluminate was prevented by the presence of CeO2 dispersed on alumina. The promoting effect of noble metals included a decrease in the reduction temperatures of NiO species interacting with the support, due to the hydrogen spillover effect. It was seen that the addition of noble metal stabilized the Ni sites in the reduced state along the reforming reaction, increasing the ethanol and glycerol conversions and decreasing the coke formation. The higher catalytic performance for the ethanol steam reforming at 600 °C and glycerol steam reforming was obtained for the NiPd and NiPt catalysts, respectively, which presented an effluent gaseous mixture with the highest H2 yield with reasonably low amounts of CO.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 12, June 2009, Pages 5049–5060
نویسندگان
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