کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1279178 1645388 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Self-ignition combustion synthesis of LaNi5 at different hydrogen pressures
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Self-ignition combustion synthesis of LaNi5 at different hydrogen pressures
چکیده انگلیسی

In this paper, we describe the self-ignition combustion synthesis (SICS) of LaNi5 utilizing the hydrogenation heat of metallic calcium at different hydrogen pressures, and focus on the effect of hydrogen pressure on the ignition temperature and the initial activation of hydrogenation. In the experiments, La2O3, Ni, and Ca were dry-mixed, and then heated at 0.1, 0.5, and 1.0 MPa of hydrogen pressure until ignition due to the hydrogenation of calcium. The products were recovered after natural cooling for 2 h. The results showed that the ignition temperature lowered with hydrogen pressure. The products changed from bulk to powder with hydrogen pressure. This was probably caused by volume expansion due to hydrogenation at higher pressure. The product obtained at 1.0 MPa showed the highest hydrogen storage capacity under an initial hydrogen pressure of 0.95 MPa. The results of this research can be applied as an innovative production route for LaNi5 without the conventional melting of La and Ni.


► Combustion synthesis of LaNi5 at different hydrogen pressures.
► Ignition temperature lowered with hydrogen pressure.
►  Products changed from bulk to powder with hydrogen pressure.
► Initial activity depended on the hydrogen pressure charged in the production.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 14, July 2011, Pages 8604–8609
نویسندگان
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