Reversible performance loss induced by sequential failed cold start of PEM fuel cells

This study correlates the post start cell performance and impedance with the cold start process in the subzero environment. The sequential failed cold starts are deliberately conducted as well as the start at small current density. Here the failed cold start means the cell voltage drops to or below zero within very short time during the start process. It is found that there are reversible performance losses for the sequential failed cold starts, while not obvious degradation and no recovery happen for the start at small current density. Using the thin film and agglomerate model, it is confirmed that this is due to the water blocking effect. Comparing the results from different start processes, a model with respect to the shifting of reactive region within the catalyst layer is applied to explain that the reversible performance loss is associated with the amount of the generated water or ice and the water location or distribution during cold start. The relationship of the cold start performance at high current density and the pore volume in the catalyst layer is also discussed.

► The post start performance is correlated with the cold start process.
► Water blocking effect within CL is the reason for the reversible performance loss.
► The loss depends on the water amount and distribution during the start process.
► The findings encourage two strategies for the cold start of PEM fuel cells.