کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299116 1498765 2012 22 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Heavier group 14 complexes with anionic P-donor ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Heavier group 14 complexes with anionic P-donor ligands
چکیده انگلیسی

The heavier group 14 elements Ge, Sn and Pb form a wide array of complexes with anionic P-donor ligands. This review surveys the synthesis, structures and, where pertinent, reactions of this class of compound; while the review is intended to be comprehensive in its coverage, emphasis is placed on the literature since 2000. For the purposes of the review ligands are classified according to the location of the negative charge: i.e. localized at phosphorus (e.g. (di)organophosphides, organophosphinidenes), localized on an atom adjacent to phosphorus (e.g. phosphinomethanides), or remote from the phosphorus center (e.g. tertiary phosphine functionalized alkoxides). These compounds adopt an impressive diversity of structures in the solid state and frequently exhibit unusual dynamic behavior in solution.


► Comprehensive review of complexes between anionic P-donor ligands and Ge, Sn or Pb.
► Emphasis on synthetic and structural aspects and dynamic behavior.
► Considerable structural diversity ranging from two-coordinate, electron-deficient species to multinuclear clusters.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 256, Issues 23–24, December 2012, Pages 2972–2993
نویسندگان
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