کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299246 1498784 2011 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Metallosurfactants of bioinorganic interest: Coordination-induced self assembly
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Metallosurfactants of bioinorganic interest: Coordination-induced self assembly
چکیده انگلیسی

This review covers selected surfactant ligands that undergo a change in aggregate morphology upon coordination of a metal ion, with a particular focus on coordination-induced micelle-to-vesicle transitions. The surfactants include microbially produced amphiphilic siderophores, as well as synthetic amphiphilic ligands. The mechanism of the metal-induced phase change is considered in light of the coordination chemistry of the metal ions, the nature of the ligands, and changes in molecular geometry that result from metal coordination. Of particular interest are biologically produced amphiphiles that coordinate transition metal ions and amphiphilic ligands of relevance to bioinorganic chemistry.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 255, Issues 7–8, April 2011, Pages 678–687
نویسندگان
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