کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1299711 | 1498844 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Aryloxo and thiolato vanadium complexes as chemical models of the active site of vanadium nitrogenase
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Aryloxo and thiolato vanadium complexes as chemical models of the active site of vanadium nitrogenase Aryloxo and thiolato vanadium complexes as chemical models of the active site of vanadium nitrogenase](/preview/png/1299711.png)
چکیده انگلیسی
This review describes recent advances in the synthesis and structural characterization of O- and S-rich ligated vanadium complexes with coligands relevant to the dinitrogen fixation process. Two classes of vanadium complexes: phenolato and thiolato are demonstrated, in aspect of ability to binding nitrogenous species. Examination of their X-ray structures allowed one to correlate the influence of O- and S-ligands at the vanadium site on the ability to bind N2-intermediates. In such simple systems, the interactions of the vanadium center with reduced and protonated N2 intermediates may help us develop an understanding of how nitrogenase functions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 249, Issues 21–22, November 2005, Pages 2144–2155
Journal: Coordination Chemistry Reviews - Volume 249, Issues 21–22, November 2005, Pages 2144–2155
نویسندگان
Zofia Janas, Piotr Sobota,