کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299715 1498844 2005 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Engineering of octacyanometalate-based coordination networks towards functionality
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Engineering of octacyanometalate-based coordination networks towards functionality
چکیده انگلیسی

The design and construction of new supramolecular coordination compounds based on octacyanometalate [M(CN)8]3−/4− (M = Mo and W) building blocks of potential utility as functional materials has received considerable attention over the recent years. The research in this field has resulted in the cyano-bridged polynuclear octacyanometalate-based molecules and polymeric coordination networks which behave like molecular magnets and photo-induced magnetic materials. This article surveys the superstructural complexity of some coordination frameworks built by multidirectional non-rigid octacyanometalate anions as linkers in self-assembly with convergent Mn(II,III), Co(III), Cu(II) and Pt(II) complexes with polyamine, diimine and Schiff-base blocking ligands. The role of intermolecular directional forces in propagation of M–CN–M′ linkages into the architectures of various dimensionalities and topologies is pointed out. The network topologies are outlined and the structure/property relationship is discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 249, Issues 21–22, November 2005, Pages 2203–2221
نویسندگان
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