کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300076 1498830 2007 28 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The photophysics and photochemistry of cofacial free base and metallated bisporphyrins held together by covalent architectures
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The photophysics and photochemistry of cofacial free base and metallated bisporphyrins held together by covalent architectures
چکیده انگلیسی

This review focuses on the photophysical properties of bisporphyrin systems held in a face-to-face configuration by covalent bonds via flexible or rigid spacers and metal–metal bonds. The cofacial arrangement induces intramolecular bismacrocycle interactions promoting basic photophysical events such as excitonic interactions and energy and electron transfers. These events are relevant to mimic light harvesting and reactor devices known for photosynthesis in plants, and can be monitored by luminescence and flash photolysis methods.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 251, Issues 3–4, February 2007, Pages 401–428
نویسندگان
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