کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300683 1498813 2008 22 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solution structure, dynamics and speciation of perfluoroaryl boranes through 1H, 11B and 19F NMR spectroscopy
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Solution structure, dynamics and speciation of perfluoroaryl boranes through 1H, 11B and 19F NMR spectroscopy
چکیده انگلیسی

Multinuclear NMR spectroscopy has been used to study the solution properties of several perfluoroaryl borane derivatives. The information obtained from all the NMR active isotopes present in these molecules made it possible to establish not only chemical identity, structure and dynamics of their reaction products, but also the complexity of the solution speciation. In other words, multinuclear NMR helped in unravelling the real forms in which they are present in solution, that in some cases can change dramatically according to even slight changes of the solution conditions. Examples will be presented related to the chemistry of tris(pentafluorophenyl)borane, B(C6F5)3, and bis(pentafluorophenyl)borinic acid, B(C6F5)2OH.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 252, Issues 21–22, November 2008, Pages 2292–2313
نویسندگان
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