کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301546 1498840 2006 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The coordination chemistry of actinides in ionic liquids: A review of experiment and simulation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The coordination chemistry of actinides in ionic liquids: A review of experiment and simulation
چکیده انگلیسی

Ionic liquids (ILs) have found widespread use in biochemical, electrochemical, catalytic, and synthetic applications, and have recently been applied to important areas of f-element chemistry. This review highlights the use of ILs in separation schemes for the sequestration of actinide ions (including lanthanides, where appropriate, as stand-ins for actinide ions), the solid-state chemistry of actinide complexes containing imidazolium cations, and the spectroscopy and electrochemistry of actinide cationic and anionic species. Particular emphasis is placed on the coordination environments that are present under a variety of conditions, such as acidic and basic tetrachloroaluminate melts. Also, this review touches on the recent use of computer simulations to elucidate the microscopic interactions that result in the preferential solvation of actinide ions in ILs.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 250, Issues 7–8, April 2006, Pages 755–764
نویسندگان
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