کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305549 | 1499168 | 2014 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, characterization, and electrochemical properties of μ-oxalate bridged vanadium(III) and (IV) dimers incorporating the Kläui ligand, CpPORCo (R = Me, Et) Synthesis, characterization, and electrochemical properties of μ-oxalate bridged vanadium(III) and (IV) dimers incorporating the Kläui ligand, CpPORCo (R = Me, Et)](/preview/png/1305549.png)
• Oxalate bridged vanadium(IV) dimers were synthesized and characterized.
• Electrochemical analysis of oxalate bridged vanadium(IV/IV) and (III/IV) dimers.
• X-ray crystallographic studies of novel vanadium(IV/IV) and (III/IV) dimers.
• NMR and EPR studies of novel vanadium(IV/IV) and (III/IV) dimers were conducted.
• Novel vanadium(IV/IV) and (III/IV) dimers have potential as oxidation catalysts.
Three novel dimeric vanadium μ-oxalate bridged complexes bearing methoxy (R = OMe) and ethoxy (R = OEt) versions of the CpPORCo− (η5-cyclopentadienyltris-(dialkylphosphito-κ1P) cobaltate(III), Kläui) ligand have been synthesized and presented along with previously synthesized complexes. Of specific interest are the dimeric vanadium(IV) complexes of each, [(CpPORCo)VO]2(μ-O4C2). The complexes were characterized via magnetic, spectral, and X-ray diffraction studies with a focus on electrochemical analysis.
Several dimeric vanadium μ-oxalate bridged complexes bearing methoxy (R = OMe) and ethoxy (R = OEt) versions of the η5-cyclopentadienyltris-(dialkylphosphito-κ1P) colbaltate(III) ligand have been synthesized. Of specific interest are the dimeric vanadium(IV) complexes of each, [(CpPORCo)VO]2(μ-O4C2). The complexes were characterized via magnetic, spectral, and X-ray diffraction studies.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 420, 24 August 2014, Pages 159–165