کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1307763 1499155 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, crystal structure and electrochemical study of (μ-κ2C:κ2S-NHC+-CS)[Fe2(CO)6]− generated from the reaction of NHC+-CS2− with Fe3(CO)12
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, crystal structure and electrochemical study of (μ-κ2C:κ2S-NHC+-CS)[Fe2(CO)6]− generated from the reaction of NHC+-CS2− with Fe3(CO)12
چکیده انگلیسی


• NHC+-CS2− (1) and (μ-κ2C:κ2S-NHC+-CS)[Fe2(CO)6]− (2) have been synthesized.
• They have been fully characterized by EA, IR and NMR.
• They have been structurally determined by X-ray crystallography.
• Electrochemical study on 2 reveals that complex 2 can catalyze H2 production.

Reaction of zwitterionic salt NHC+-CS2− (1), prepared from 1,3-diallylbenzimidazol-2-ylidene and CS2, with Fe3(CO)12 affords 2, (μ-κ2C:κ2S-NHC+-CS)[Fe2(CO)6]−. Two new compounds have been fully characterized by EA, IR, 1H NMR and 13C NMR spectroscopy and structurally determined by X-ray crystallography. Electrochemical study of 2 has demonstrated that using HOAc as a proton source complex 2 can efficiently catalyze H2 production.

NHC+-CS2− (1) and (μ-κ2C:κ2S-NHC+-CS)[Fe2(CO)6]− (2) have been synthesized and fully characterized by EA, IR and NMR. They have been structurally determined by X-ray crystallography. Electrochemical study on 2 reveals that complex 2 can catalyze H2 production.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 434, 1 August 2015, Pages 92–96
نویسندگان
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